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The noble Della Gherardesca family began practicing viticulture in the late 1600s on their land in Bolgheri, but things began to change under the guidance of Guido Alberto Della Gherardesca (1780-1854). He was passionate about viticulture. He was appointed majordomo of Grand Duke Leopold II and then dedicated himself to enology in his family's land in Maremma.
In the 1930s, the property was inherited by Carlotta Della Gherardesca Antinori (Piero Antinori's mother) and her sister, who was married to Mario Incisa Della Rocchetta (who received the nearby Tenuta San Guido).
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